Lots of classes duo well together. Don't try to min/max for the best combo. If you do, then it's definitely enchanter/shaman - at least around 40+. But both are tedious at lower/mid level and both require a lot of work/skill.
Necro/mage is solid from the start. What class do you currently play? Just complement your current toon if you already enjoy your class instead of starting over.
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