I've found that going from windowed mode to fullscreen is nothing more than cross your fingers and hope it works out for the best. I have about a 50% success rate it seems with alt+enter. When it fails, it always gives an error message, but I usually just log in and try again. Of course I always end up kicking myself because I'll alt + tab to go check a site or something and end up right back in windowed mode 5 minutes after going full screen.
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