Among the 4 Elemental Mastery staves:
Water - Phinigel - Relatively easy to obtain, find a puller and 3~ pet classes to chain pet him to death
Air - Stupid PoAir Quest that requires drops from Islands 6-8 including both 7 and 8 bosses. Don't hold your breath trying to get this.
Fire - PoHate trash (or does this even drop yet?). I don't think I've ever seen one drop, although I haven't spent much time in Hate.
Earth - Innoruuk drops this, and if you have this, you basically have your epic rendering all the other staves useless since epic pet is far superior.
tl;dr Only the water one is feasibly attainable unless you raid a lot.
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