I can't say I ever did it for EXP but it will be new and fun.
Get level 52/53 for Call of Karana and Glamour of Tunare. Once you have those, charming is a breeze plus in an outdoor zone it's trivial.
The main concern in WW is roaming dragons (get factioned and it's not an issue) and roaming burrowers/hounds (the former being much more annoying). However I think a decent strategy in that zone may be to charm a mob, throw it at a burrowers (level 61 mob that doesn't summon), let it get low, break it and nuke your pet dead, find a new pet and send on burrower. I believe they rip through the animal mobs pretty quickly.
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