Chilling Embrace does the most damage at level 39, 40/tick for 16 ticks is 640 damage for 200 mana. 3.2 dpm no chance to break root.
Boil Blood is 24 damage for max of 21 ticks or 504 damage for 150 mana, 3.36 dpm is most efficient.
Scourge can break root and does 544 damage over 21 ticks for 170 mana, 3.2 dpm. This spell is inferior to Chilling Embrace, it can break root and it takes longer.
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