Two very powerful duo options:
Monk + Shaman (2x Iksar)
Enchanter + Cleric (2x Dark Elf, or 2x High Elf)
Iksar starting zone is pretty self-contained, you can level quite a ways in it before you have to travel at all.
Similarly, High Elf starting zone is right by Crushbone, and Dark Elf starting area is right by the Commonlands.
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