Here are my suggestions:
Shaman/monk is a good duo that can operate inside dungeons.
Cleric/tank(I would choose sk but paladin or warrior would work also) can duo, but more importantly you always have the makings to start up a group.
Necro/rogue is great for outdoor duoing as the necro can either keep aggro with darkness/dots or can darkness/fear while the rogue and pet kill the mob.
Mage/mage to pet things down, although mages don't improve as much from 50-60 as other classes.
Bards don't work as well in duos as some classes b/c many of their songs work best in a full group b/c they benefit all members of the group. Bards can solo, but they way in which they solo does benefit much (if at all) by having another member. A bard/cleric could work but not that well because bards do not tank particularly well nor dps particularly well. However with this duo you at least have 2 good classes for starting up a full group since a bard can handle the crowd control.
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