The proc rate at 255 dexterity is 2 procs per minute mainhand - one per minute offhand. Average. Strings of lucky procs and strings of unlucky droughts are gonna happen regardless of your absolute dexterity but rates will always settle towards the average.
Anything below 255 scales downward. To what degree that scales down (linear vs otherwise) I’m not absolutely certain and I don’t want to make up numbers but it is noticeable.
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