I think the CHA cap for extracting best prices is 105 but could be wrong. It all depends. If you're a troll with a starting CHA in the 50's but you can afford a +50 CHA set of equipment just for selling and you tend to kill shit in areas that drop decent vendor loot it's probably worth it. The only question is how long it takes to recoup the cost of the CHA gear you're hauling around with you and whether it ever limits your carrying capacity.
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