[guineapig]

To get you started try to obtain the following items through auction, jewelrycraft or just camping them:

platinum star ruby veil +9
(2X) electrum star ruby ring +14
platinum cat's eye neck. +9
(2X) golden cat's eye bracer. +14
crude stein +15
noble's robes +6
siryn hair hood +13
(2x) Opalline Earring +10
Rod of Insidious Glamour +12
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Total = 102

Get a buff:
radiant visage (buff) +30
(the shaman charisma buff is even better I think)
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grand total = 132 (or better)

If you are a high elf you can put all your starting stats into stamina and int and still have 90 base charisma which would already put you at 222 Charisma.

Hope this helps somewhat.