Supposedly, Pain soul is supposed to spawn 1/2 as many times as rotting skeleton.
Whether those numbers (.25 and .5%) are accurate or not is hard to say. Most people tend to camp RS for 8-12 hours and PS for 16ish.
RS took me 12 hours on my main. When getting my alt his vp key, I killed the PH once and spawned two Rotting Skeleton's back to back. Getting two in 18 minutes is probably much more rare than you not getting one in 26 hours.
Dolic
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