Bind wound + canni is great synergy, especially when you have someone with 201+ skill in camp between pulls.
In general you want to slow most mobs, but use your common sense. If you're in KC with a 55+ tank you don't need to slow mobs like spectral curate that will die in 20 seconds (and spend half of that time attempting to cheal).
That said, don't wear too many hats. Sure you can buff, heal, slow, cc, offtank, dot BUT don't do it all at once; save some work for the others in the group! You can defer some healing to the necromancers, the Druid can be in charge of regen, etc. similarly don't waste mana on buffs of little value (does the wizard really need agility!?). Don't skimp where they are required (that under geared monk will tank a lot better with an AC buff on).
Most of all just get out there, make friends, have fun and see what works for you.
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