I believe the closest arrows are in Thurg for Velious.
I would recommend fear kiting Cougars starting around 33. There is also the option for the Tizmak warriors in great divide which provides easy access to Thurg for arrows.
The splitpaw gnolls are nice for money and exp; I wouldn't sell the scrolls though and instead go to Qeynos for the exp quest. Turning them in singles gives great exp if you don't mind auto-running to Qeynos once you gather 3-4 scrolls. I would usually do it at 3 scrolls to avoid getting too many repeated scrolls (lore) waiting for the 4th one to drop. I did bow kiting on the gnolls with my ranger as well as bow-rooting inside splitpaw if the spawns outside were camped. You can snag Quillmane/Coloth Meadowgreen in SK as well on tracking for some decent loot. It is also to keep down the place holder for Groi Gutblade if no one is camping him while doing splitpaw entrance. Arrows are easy to restock in this area as well.
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