Junk-buffing your charmed pet isn't really possible unless it's a caster that has buffed itself before you charm it. When you charm a mob, charm will be the first buff on its list. No matter how many buffs you then cast on it, charm will remain on top. Then when charm wears off, that top slot will be empty. When you charm it again, charm goes in the first slot again. One dispel will always get rid of charm unless the mob had its first slots filled with its own buffs before you charmed it the first time around. You can't buff a hostile mob.
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